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Knowledge Library · 4 topics

Ohmic Drop and Potentiostat Fundamentals

Potentiostat stability, reference-electrode and cable parasitics, the effect of ohmic drop on measurements and its measurement and correction with ZIR/current interrupt: the prerequisites of every sound measurement.

Battery – Application Note 4SP-150 → SP-150eSP-50 → SP-50eVMP2 → VMP-3eVMP3 → VMP-3eVMP300VSP → VSP

Potentiostat stability: why does oscillation occur, how is the bandwidth chosen?

Effect of the control loop, cell capacitance and cable effects on stability; when to change the bandwidth (stability) setting in EC-Lab®.

Sections of the note: Introduction · POTENTIOSTAT, BASIC PRINCIPLES · WHERE ARE THOSE OSCILLATIONS COMING FROM ? · PRACTICAL SITUATIONS · THE BANDWIDTH PARAMETER · STABILITY CRITERION FOR A CAPACITIVE CELL

Current model: The SP-150 has been replaced by the SP-150e.
Current model: The SP-50 has been replaced by the SP-50e.
Current model: The VMP2 has been discontinued; its current counterpart is the VMP-3e.
Current model: The VMP3 has been discontinued; its current counterpart is the 16-channel VMP-3e.
Current model: The VSP is still available in the Essential range; for energy applications the VSP-3e is recommended.
Related products:SP-300VMP-3eEC-Lab®
Download PDF Source: biologic.net · Updated: December 19, 2023
Corrosion – Application Note 27

Ohmic drop 1: How does IR drop affect measurements?

Effect of solution resistance and electrode position on CV, Tafel and EIS; estimating the magnitude of the ohmic drop.

Sections of the note: Introduction · Steady-State Conditions · Voltammetry · Tafel Plot · Another Example · Impedance Measurements

Related products:EC-Lab®
Download PDF Source: biologic.net · Updated: May 29, 2024
Battery – Application Note 28

Ohmic drop 2: Which techniques measure IR drop?

Comparison of current interrupt (CI), EIS (ZIR) and positive feedback methods; EC-Lab® application.

Sections of the note: Introduction · EIS Measurement · Current Interrupt Method · Battery Analysis · EIS Measurements · Current Interrupt Method

Related products:EC-Lab®SP-300
Download PDF Source: biologic.net · Updated: May 5, 2023
Battery –  Application Note 29

Ohmic drop 3: How are ZIR techniques used correctly?

Automatic compensation of the resistance measured with ZIR, percentage setting and over-compensation risks; manual and EIS-based compensation.

Sections of the note: Introduction · ZIR techniques · High frequency equivalent circuit of an electrochemical impedance · Equivalent circuit of an electro-chemical impedance · High frequency equivalent circuit of an electrochemical faradaic impedance · RΩ measurement in the simplest case

Related products:EC-Lab®SP-300
Source: biologic.net · PDF (manufacturer) · Updated: January 31, 2024

Products related to this class

SP-300
Bio-LogicPremium

SP-300

Fast, accurate, stable and modular — grows with your research
  • 2 slots: second channel, bipotentiostat (RRDE) or internal booster
  • Internal booster boards: ±1 A/±48 V, ±2 A/±30 V, ±4 A/[-3;14] V, ±10 A/[-1;6] V
  • EIS 10 µHz – 11 MHz
SP-200
Bio-LogicPremium

SP-200

Portable, research-grade single-channel potentiostat
  • ±500 mA maximum current, 9 current ranges (10 nA – 1 A)
  • EIS option: 10 µHz – 11 MHz
  • ±100 fA accuracy on the 1 pA range with the ULC option
EC-Lab®
Bio-Logic

EC-Lab®

Over 30 years of development: the reference software in electrochemistry
  • 80+ techniques, experiment sequence builder
  • EIS 10 µHz – 11 MHz, patented drift correction
  • Z Fit: 150+ circuits, 14 elements

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