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Popular topics · Measurement quality and accuracy

How is the EIS accuracy contour plot used to plan a measurement?

The accuracy contour supplied with each potentiostat shows which frequencies can be measured within a stated modulus and phase error for a given impedance range.

Key points

  • The coloured areas show |Z| (%) and phase (°) error bands as a function of impedance modulus and frequency; in the example the error is below 0.3% and 0.3° in the innermost area and rises to 1% / 1° and 3% / 3° in the outer bands.
  • When the Bode modulus curve of a circuit (e.g. R1 + R2/C2) is drawn over the contour, the band of each frequency point can be read; points outside the bands also appear wrong in the Nyquist plot.
  • The contour is valid only for the stated conditions (excitation amplitude, temperature, averaging, etc.) and is an image of the instrument's capability; cables and accessories must also be taken into account.
  • Details of how to read it are in Bio-Logic AN54.

Figures

Measurement point on the accuracy contour: in the green region |Z| error is below 0.3% and phase error below 0.3°; outside the limits the error grows quickly.
Figure 1. Measurement point on the accuracy contour: in the green region |Z| error is below 0.3% and phase error below 0.3°; outside the limits the error grows quickly.

Images: Bio-Logic Science Instruments; taken from the source article.

Related application notes

Related curriculum module: Electrochemical Impedance Spectroscopy (EIS)

Source: Bio-Logic Learning Center, “How to use electrochemical impedance spectroscopy (EIS) accuracy contour plots” · Source updated: November 18, 2024
Copyright of the images and the original text belongs to Bio-Logic SAS.

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